Implemented WebEx with ADFS SSO (Windows 2012R2) successfully, and found these articles helpful:
Initial Setup:
https://cisco-support.webex.com/guest/articles/en_US/Usability_FAQs/WBX63102/myr=false
Those guides do not go over configuring sign-out. This can be accomplished with the WSFederation sign-out URL documented here:
And configuring your ADFS server with:
1. Go to AD FS Manager – Trust Relationships – Relying Party Trusts – <your party trust> properties
2. Under the Endpoints tab, click Add SAML…
3. Endpoint Type = SAML Logout, Binding = POST, Trusted URL = https://myadfsserver.domainname.com/adfs/ls/?wa=wsignout1.0